1. Identification	

Product identifier used on the label
	
5 Gallon Pail Damtite ClearShield
1 Gallon Bottle Damtite ClearShield

Recommended use and restriction on use
Recommended use: Water repellent.
Restrictions on use: None known. 	

Manufacturer/Importer/Supplier/Distributor Information

Supplier
Company Name:	Wall Firma Inc. / Damtite Waterproofing	
Address:	733 E. Main St. 
Monongahela, PA 15063	
Telephone:+1 (724)258-6873	
Fax:+1 (724)258-3318	

Emergency telephone number: +1 (800) 424-9300 CHEMTREC

2. Hazard(s) identification	

Hazard Classification
Health HazardsSerious eye irritation	Category 3	

Label Elements	

Hazard Symbol:		

Signal Word:	Warning	

Hazard Statement:	Causes eye irritation.
Causes mild skin irritation.	

Precautionary Statement		
Prevention:	Use personal protective equipment as required.	

Response:	IF IN EYES: Rinse cautiously with water for several minutes. IF ON SKIN: Wash with plenty of soap and water. If exposed or concerned: Get medical advice/attention. 	

Storage:	Store in a well-ventilated place.  	

Disposal:	Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. 	

Other hazards which do not result in GHS classification:	Chemical compounds containing silicon - hydrogen bonds (SiH). This product may generate hydrogen gas. For further information, refer to Section 10: "Stability and Reactivity". 

3. Composition/information on ingredients	

Mixtures

Chemical Identity	Common name and synonyms	CAS number	Content in percent (%)*	
Poly(oxy-1,2-ethanediyl), α-tridecyl-ω-hydroxy-		24938-91-8<2%	Acetic acid	ACIDE ACETIQUE, 	64-19-70.5 - 1.5%	Ethanol	ALCOOL ETILICO PURO E DENATURADO, 	64-17-50.1 - 1%	* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

Composition Comments:Aqueous emulsion of Polyorganosiloxanes. 
4. First-aid measures	

General information: 	For further information refer to section 8 "Exposure-controls/personal protection". 	

Ingestion: 	Do not induce vomiting. Rinse mouth thoroughly. Get medical attention if symptoms occur. 	

Inhalation:	Under normal conditions of intended use, this material is not expected to be an inhalation hazard. 	

Skin Contact:	Immediately wipe excess material off skin with a dry cloth; then wash skin with plenty of soap and water. Seek medical attention if irritation develops or persists. 	

Eye contact:	In case of contact, immediately absorb excess with clean absorbent cloth or cotton. Then, hold eyelids open and flush with a steady, gentle stream of water for at least 15 minutes. Seek medical attention if irritation develops or persists or if visual changes occur. 	

Most important symptoms/effects, acute and delayed

Symptoms:	None known. 	

Hazards:	No specific recommendations.	

Indication of immediate medical attention and special treatment needed 

Treatment:	No specific recommendations. 	

5. Fire-fighting measures	

General Fire Hazards:	No specific recommendations. 	

Suitable (and unsuitable) extinguishing media

Suitable extinguishing media:	Dry chemical, alcohol resistant foam or carbon dioxide (CO2). 

Unsuitable extinguishing media:	Do not use water jet as an extinguisher, as this will spread the fire. Do not use alkaline powders. 	

Specific hazards arising from the chemical:	Material will burn if water evaporates from emulsion, and it is heated above its flash point. Hazardous Decomposition Products : formaldehyde, oxides of carbon and silica. For further information, refer to Section 10: "Stability and Reactivity". 	

Special protective equipment and precautions for firefighters

Special fire fighting procedures:	Water spray should be used to cool containers. 

Special protective equipment for fire-fighters:	Firefighters should wear NIOSH/MSHA approved self-contained breathing apparatus and full protective clothing. 	

6. Accidental release measures	

Personal precautions, protective equipment and emergency procedures:	Wear appropriate personal protective equipment. See Section 8 of the MSDS for Personal Protective Equipment. Avoid contact with bases. Eliminate all sources of ignition. 	

Methods and material for containment and cleaning up:	Avoid contact with bases. Absorb with inert material.  Scrape up and place in appropriate closed container see Section 7 of the MSDS. 	

Notification Procedures:	Caution: Contaminated surfaces may be slippery. For waste disposal, see section 13 of the MSDS. 	

Environmental Precautions:	Do not allow to enter drains, sewers or watercourses. 

7. Handling and storage	

Precautions for safe handling:	Provide adequate ventilation if fumes or vapors are generated. Do not mix with incompatible materials. For further information, refer to Section 10: "Stability and Reactivity". Read and follow manufacturer's recommendations. 	

Conditions for safe storage, including any incompatibilities:	Store in original vented container. Store in a cool, dry place with adequate ventilation. Keep away from incompatible materials, open flames, and high temperatures. 	

8. Exposure controls/personal protection	

Control Parameters
Occupational Exposure Limits
Chemical Identity	Type	Exposure Limit Values	Source	
Acetic acidSTEL15 ppm	 	US. ACGIH Threshold Limit Values (01 2010)	TWA10 ppm	 	US. ACGIH Threshold Limit Values (01 2010)	STEL15 ppm	37 mg/m3	US. NIOSH: Pocket Guide to Chemical Hazards (2005)	REL10 ppm	25 mg/m3	US. NIOSH: Pocket Guide to Chemical Hazards (2005)	PEL10 ppm	25 mg/m3	US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006)	TWA10 ppm	25 mg/m3	US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)	TWA10 ppm	25 mg/m3	US. Tennessee. OELs. Occupational Exposure Limits, Table Z1A (06 2008)	AN ESL	10 ppb	US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) (02 2009)	ST ESL	100 ppb	US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) (02 2009)	AN ESL	25 µg/m3	US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) (02 2009)	ST ESL	250 µg/m3	US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) (02 2009)	TWA PEL10 ppm	25 mg/m3	US. California Code of Regulations, Title 8, Section 5155. Airborne Contaminants (09 2006)	STEL15 ppm	37 mg/m3	US. California Code of Regulations, Title 8, Section 5155. Airborne Contaminants (09 2006)	Ceiling40 ppm	 	US. California Code of Regulations, Title 8, Section 5155. Airborne Contaminants (09 2006)	EthanolSTEL1,000 ppm	 	US. ACGIH Threshold Limit Values (01 2010)	REL1,000 ppm	1,900 mg/m3	US. NIOSH: Pocket Guide to Chemical Hazards (2005)	PEL1,000 ppm	1,900 mg/m3	US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006)	TWA1,000 ppm	1,900 mg/m3	US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)	TWA1,000 ppm	1,900 mg/m3	US. Tennessee. OELs. Occupational Exposure Limits, Table Z1A (06 2008)	AN ESL	1,000 ppb	US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) (02 2009)	ST ESL	10,000 ppb	US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) (02 2009)	ST ESL	18,800 µg/m3	US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) (02 2009)	AN ESL	1,880 µg/m3	US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) (02 2009)	TWA PEL1,000 ppm	1,900 mg/m3	US. California Code of Regulations, Title 8, Section 5155. Airborne Contaminants (09 2006)	

Appropriate Engineering Controls	No specific recommendations. 	

Individual protection measures, such as personal protective equipment	

General information:	Provide sufficient ventilation during operations which cause vapor formation. 	

Eye/face protection:	Wear approved safety glasses. 	

Skin Protection
Hand Protection:	Protective gloves are recommended. 	

Other:	Wear suitable protective clothing. 	

Respiratory Protection:	No protection is ordinarily required under normal conditions of use and with adequate ventilation. 	

Hygiene measures:	Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 	

9. Physical and chemical properties	

9.1 Information on basic physical and chemical properties:

Appearance
Physical state:	Liquid 	
Form:Emulsion 	
Color:Whitish.	
Odor:Slight amine.	
Odor threshold:No data available.	
pH:10 
Melting point/freezing point:	>= 32 °F (0 °C)Water.	
International Inventories:	>= 212 °F (100 °C) 	
Flash Point:> 212 °F (100 °C) Aqueous liquid for which the organic components have flash point > 100 °C.	
Evaporation rate:No data available.	
Flammability (solid, gas):	No data available.	
Flammability limit - upper (%):	No data available.	
Flammability limit - lower (%):	No data available.	
Vapor pressure:	No data available.	
Vapor density:	No data available.	
Relative density:	1 (68 °F (20 °C)) Approximate	
Solubility(ies)	
Solubility in water:	Dispersible 	
Solubility (other):	Ketones: Soluble
Ethanol.: Soluble
Diethylether.: Insoluble
Trichloroethylene.: Insoluble
White-spirit.: Insoluble	
Partition coefficient (n-octanol/water):	No data available.	
Auto-ignition temperature:	No data available.	
Decomposition temperature:	No data available.	Viscosity:	24 mm2/s (77 °F (25 °C)) 	

Other information 
Oxidizing properties:	According to the data on the components Not considered as oxidizing. (evaluation by structure-activity relationship) 
10. Stability and reactivity	

Reactivity:	No data available.	

Chemical Stability:	Material is stable under normal conditions. 	

Possibility of Hazardous Reactions:	This product may generate hydrogen gas. 

Conditions to Avoid:	Avoid heat, sparks, open flames and other ignition sources. 	

Incompatible Materials:	A fire or explosion hazard arises because highly flammable gas (hydrogen) is released when it is in contact with : Strong oxidizers, strong bases and chemical compounds with mobile hydrogen, in the presence of metal salts and complexes. 	

Hazardous Decomposition Products:	Thermal decomposition may liberate dimethylcyclosiloxanes. This product can form formaldehyde vapors when heated to temperatures above 150 degrees C in the presence of air. 	

11. Toxicological information	

Information on likely routes of exposure
Ingestion:	No data available.	

Inhalation:	No data available.

Skin Contact:	Mildly irritating to skin with prolonged exposure. 

Eye contact:	May cause minor irritation on eye contact. 

Symptoms related to the physical, chemical and toxicological characteristics
Ingestion:	No data available.	

Inhalation:	No data available.

Skin Contact:	No data available.

Eye contact:	No data available.

Information on toxicological effects

Acute toxicity (list all possible routes of exposure)

Oral
Product:	No data available.	

Dermal
Product:	No data available.	

Inhalation
Product:	No data available.	

Repeated Dose Toxicity
Product:	No data available.	

Skin Corrosion/Irritation
Product:	No data available.

Serious Eye Damage/Eye Irritation
Product:	No data available.	

Respiratory or Skin Sensitization
Product:	Not a skin sensitizer. 

Carcinogenicity
Product:	No data available.

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:

EthanolOverall evaluation: Carcinogenic to humans. 	

US. National Toxicology Program (NTP) Report on Carcinogens:
EthanolKnown carcinogen. 	

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):
No carcinogenic components identified

Germ Cell Mutagenicity

In vitro
Product:	No data available.

In vivo
Product:	No data available.

Reproductive Toxicity
Product:	No data available.

Specific Target Organ Toxicity - Single Exposure
Product:	No data available.

Specific Target Organ Toxicity - Repeated Exposure
Product:	No data available.

Aspiration Hazard
Product:	No data available.

Other Effects:	No data available.	

12. Ecological information	

Ecotoxicity:	

Acute hazards to the aquatic environment:

Fish
Product:	No effects expected (assessment based on ingredients). 	

Aquatic Invertebrates
Product:	No data available.	

Chronic hazards to the aquatic environment:

Fish
Product:	No data available.	

Aquatic Invertebrates
Product:	No data available.	

Toxicity to Aquatic Plants
Product:	No data available.	

Persistence and Degradability

Biodegradation
Product:	The product contains inorganic compounds which are not biodegradable. The other components of the product are slowly biodegradable. 

BOD/COD Ratio
Product:	No data available.	

Bioaccumulative Potential
Bioconcentration Factor (BCF)
Product:	Will not bio-accumulate. 	

Partition Coefficient n-octanol / water (log Kow)
Product:	No data available.	

Mobility in Soil:	No data available.

Known or predicted distribution to environmental compartments
Poly(oxy-1,2-ethanediyl), α-tridecyl-ω-hydroxy-No data available.	
Acetic acidNo data available.	
EthanolNo data available.	

Other Adverse Effects:	No data available.	

13. Disposal considerations	

Disposal instructions:	Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Waste of this material should not be mixed with other waste. Provide measures such as vented bungs to ensure pressure relief in the waste container. 

14. Transport information	

This material is not subject to transport regulations.

Environmental hazards:	Not regulated.

Special precautions for user:	Packaging with a breathing/venting bung are FORBIDDEN for transport by air.

15. Regulatory information	

US Federal Regulations

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
None present or none present in regulated quantities.

CERCLA Hazardous Substance List (40 CFR 302.4):
None present or none present in regulated quantities.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories

X	Acute (Immediate)	Chronic (Delayed)	FireX	Reactive	Pressure Generating
SARA 302 Extremely Hazardous Substance
None present or none present in regulated quantities.

SARA 304 Emergency Release Notification
None present or none present in regulated quantities.

SARA 313 (TRI Reporting)
None present or none present in regulated quantities.

Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
None present or none present in regulated quantities.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):
None present or none present in regulated quantities.

US State Regulations

US. California Proposition 65
This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm.

EthanolCarcinogenic. 	
EthanolDevelopmental toxin. 	

US. New Jersey Worker and Community Right-to-Know Act
No ingredient regulated by NJ Right-to-Know Law present.

US. Massachusetts RTK - Substance List
No ingredient regulated by MA Right-to-Know Law present.

US. Pennsylvania RTK - Hazardous Substances
No ingredient regulated by PA Right-to-Know Law present.

US. Rhode Island RTK
No ingredient regulated by RI Right-to-Know Law present.

16.Other information, including date of preparation or last revision	

HMIS Hazard ID

B - Safety Glasses & Gloves 
Health	
 	
1	

Flammability	
 1	

Physical Hazards	
 1	

Personal protection	
B
Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe; *Chronic health effect	

	NFPA Hazard ID	
		
1

1

1

	
	
Flammability	

Health	

Reactivity	

Special hazard.	

Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe	

SDS Prepared by:

Wall Firma Inc. / Damtite Waterproofing
SDS Prepared on: 2015/5/15

We support worldwide Responsible Care® initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products.

IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET.